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Two-stage injection strategy was studied in dimethyl-ether homogeneous charge compression ignition engine combustion. An early direct injection, main injection, was applied to form a premixed charge followed by the second injection after the start of heat release. Experiments were carried out in a single-cylinder direct-injection diesel engine equipped with a common-rail injection system, and the combustion performance and exhaust emissions were tested with the various second injection timings and quantities. Engine speed was 1200 rpm, and the load was fixed at 0.2 MPa IMEP. Main injection timing for homogeneous mixture was fixed at −80 CAD, and the fuel quantity was adjusted to the fixed load. Second injection quantity was varied from 1 to 5 mg, and the timing was selected according to the heat release rate of the HCCI combustion without second injection.