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Scarce resources of fossil fuels and increasingly stringent exhaust emission legislation push towards a stronger focus to alternative fuels. Natural gas is considered a promising solution for small engines and passenger cars due to its high availability and low carbon dioxide emissions. Furthermore, natural gas indicates great potential of increased engine efficiency at lean-burn operation. However, the ignition of these lean air/fuel mixtures leads to new challenges, which can be met by fuel scavenged prechambers. At the Institute of Internal Combustion Engines of the Technische Universitaet Muenchen an air cooled natural gas engine with a single cylinder displacement volume of 0.5 L is equipped with a methane scavenged prechamber for investigations of the combustion process under real engine conditions. The main combustion chamber is supplied with a lean premixed air/fuel mixture.

In this project funded by the Bayerische Forschungsstiftung two fundamental investigations had been carried out: first a new N-rich liquid ammonia precursor solution based on guanidine salts had been completely characterized and secondly a new type of side-flow reactor for the controlled catalytic decomposition of aqueous NH₃ precursor to ammonia gas has been designed, applied and tested in a 3-liter passenger car diesel engine. Guanidine salts came into the focus due to the fact of a high nitrogen-content derivate of urea. Specially guanidinium formate has shown extraordinary solubility in water (more than 6 kg per 1 liter water at room temperature) and therefore a possible high ammonia potential per liter solution compared to the classical 32.5% aqueous urea solution (AUS32) standardized in ISO 22241 and known as DEF (diesel emission fluid), ARLA32 or AdBlue® .

Due to its molecular structure, methane provides several advantages as fuel for internal combustion engines. To cope with nitrogen oxide emissions high levels of excess air are beneficial, which on the other hand deteriorates the flammability and combustion duration of the mixture. One approach to meet these challenges and ensure a stable combustion process are fuelled prechambers. The flow and combustion processes within these prechambers are highly influenced by the position, orientation, number and overall cross-sectional area of the orifices connecting the prechamber and the main combustion chamber. In the present study, a water-cooled single cylinder test engine with a displacement volume of 0.5 l is equipped with a methane-fuelled prechamber. To evaluate influences of the aforementioned orifices several prechambers with variations of the orientation and number of nozzles are used under different operating conditions of engine speed and load.

In the present work the benefit of a 50 MPa gasoline direct injection system (GDI) in terms of particle number (PN) emissions as well as fuel consumption is shown on a 0.5 l single cylinder research engine in different engine operating conditions. The investigations show a strong effect of injection timing on combustion duration. As fast combustion can be helpful to reduce fuel consumption, this effect should be investigated more in detail. Subsequent analysis with the method of particle image velocimetry (PIV) at the optical configuration of this engine and three dimensional (3D) computational fluid dynamics (CFD) calculations reveal the influence of injection timing on large scale charge motion (tumble) and the level of turbulent kinetic energy. Especially with delayed injection timing, high combustion velocities can be achieved. At current series injection pressures, the particle number emissions increase at late injection timing.

In the near future, pollutant and GHG emission regulations in the transport sector will become increasingly stringent. For this reason, there are many studies in the field of internal combustion research that investigate alternative fuels, one example being oxygenated fuels. Additionally, the design of engine components needs to be optimized to improve the thresholds of clean combustion and thus reduce particulates. Simulations based on PRiME 3D® for dynamic behaviors inside the piston ring group provide a guideline for experimental investigation. Gas flows into the combustion chamber are controlled by adjusting the piston ring design. A direct comparison of regular and synthetic fuels enables to separate the emissions caused by oil and fuel. This study employed a mixture of dimethyl carbonate (DMC) and methyl formate (MeFo).

Polyoxymethylene dimethyl ethers (OME) are promising alternative diesel fuels with a biogenic or electricity-based production, which offer carbon neutral mobility with internal combustion engines. Among other e-fuels, they stand out because of soot-free combustion, which resolves the trade-off between nitrogen oxide (NOx) and soot emissions. Additionally, long-chain OME have a high ignitability, indicated by a cetane number (CN) greater than 70. This opens up degrees of freedom in the injection strategy and enables simplifications compared to the operation with fossil diesel. This study investigates the hydraulic behavior of two solenoid injectors with different injector geometry for heavy-duty applications on an Injection Rate Analyzer (IRA) in diesel and OME operation. For OME, both injectors show longer injection delays in all injection pressure ranges investigated, increasing with rail pressure.

Oxygenated synthetic fuels such as oxymethylene ether (OME) are a promising approach to reduce the emissions of diesel engines and to improve sustainability of mobility. The soot-free combustion of OME allows an optimization of the combustion process to minimize remaining pollutants. Considering the injection system, one strategy is to decrease the rail pressure, which has a positive impact on the reduction of nitrogen oxides without increasing the particle formation. Furthermore, due to the reduced lower heating value of OME compared to diesel fuel, an adaptation of the injector nozzle is recommended. This work describes a method for analyzing the injection process for OME, using the Mie scattering effect in an optically accessible heavy-duty diesel engine. The design of the 1.75 l single cylinder engine allows operation up to 300 bar peak cylinder pressure, providing optical access through the piston bowl and through a second window lateral below the cylinder head.

In this study a mixture of dimethyl carbonate (DMC) and methyl formate (MeFo) was used as a synthetic gasoline replacement. These synthetic fuels offer CO2-neutral mobility if the fuels are produced in a closed CO2-cycle and they reduce harmful emissions like particulates and NOX. For base potential investigations, a single-cylinder research engine (SCE) was used. An in-depth analysis of real driving cycles in a series 4-cylinder engine (4CE) confirmed the high potential for emission reduction as well as efficiency benefits. Beside the benefit of lower exhaust emissions, especially NOX and particle number (PN) emissions, some additional potential was observed in the SCE. During a start of injection (SOI) variation it could be detected that a late SOI of DMC/MeFo has less influence on combustion stability and ignitability. With this widened range for the SOI the engine application can be improved for example by catalyst heating or stratified mode.

In this study, a fully optically accessible single-cylinder research engine is the basis for the visualization and generation of extensive knowledge about the in-cylinder processes of mixture formation, ignition and combustion of oxygenated synthetic fuels. Previous measurements in an all-metal engine showed promising results by using a mixture of dimethyl carbonate and methyl formate as a fuel substitute in a DISI-engine. Lower THC and NOx emissions were observed along with a low PN-value, implying low-soot combustion. The flame luminosity transmitted via an optical piston was split in the optical path to simultaneously record the natural flame luminosity with an RGB high-speed camera. The second channel consisted of OH*-chemiluminescence recording, isolated by a bandpass filter via an intensified monochrome high-speed camera.

Polyoxymethylene dimethyl ethers (OME) are synthetic fuels, which offer the property of sustainability because the reactants of production base on hydrogen and carbon dioxide on the one hand, and the air pollution control in consequence of a soot-free combustion in a diesel engine on the other hand. High exhaust gas recirculation (EGR) rates are a promising measure for nitrogen oxide (NOx) reduction without increasing particle emissions because of the resolved soot-NOx trade-off. However, EGR rates towards stoichiometric combustion in OME operation reveals other trade-offs such as methane and formaldehyde emissions. To avoid these, a lean mixture with a combination of EGR and exhaust after-treatment with selective catalytic reduction (SCR) is useful. The limitation of urea dosing due to the light-off temperature of SCR systems requires heating measures.

The European Commission has released strict emission regulations for passenger cars in the past decade in order to improve air quality in cities and limit harmful emission exposure to humans. In the near future, even stricter regulations containing more realistic/demanding driving scenarios and covering more exhaust gas components are expected to be released. Passenger cars fueled with gasoline are one contributor to unhealthy air conditions, due to the fact that gasoline engines emit harmful air pollutants. One option to minimize harmful emissions would be to utilize specifically tailored, low emission synthetic fuels or fuel blends in internal combustion engines. Methyl formate and dimethyl carbonate are two promising candidates to replace or substitute gasoline, which in previous studies have proven to significantly decrease harmful pollutants.

The reduction of both harmful emissions (CO, HC, NOx, etc.) and gases responsible for greenhouse effects (especially CO2) are mandatory aspects to be considered in the development process of any kind of propulsion concept. Focusing on ICEs, the main development topics are today not only the reduction of harmful emissions, increase of thermodynamic efficiency, etc. but also the decarbonization of fuels which offers the highest potential for the reduction of CO2 emissions. Accordingly, the development of future ICEs will be closely linked to the development of CO2 neutral fuels (e.g. biofuels and e-fuels) as they will be part of a common development process. This implies an increase in development complexity, which needs the support of engine simulations. In this work, the virtual modeling of real fuel behavior is addressed to improve current simulation capabilities in studying how a specific composition can affect the engine performance.

The development of today's drivetrains focusses on the reduction of vehicles' CO2-emissions. Therefore, a drivetrain for urban and commuter traffic is under development at the Institute of Internal Combustion Engines. The concept is based on a lean-burn air cooled two-cylinder natural gas engine, which is combined with a hydraulic hybrid system. On the one hand, lean-burn combustion leads to low nitrogen oxides emissions and high thermal efficiency. On the other hand, there are several challenges concerning inflammability, combustion stability and combustion duration. An approach to optimize the combustion process is the design of the piston bowl. The paper presents the engine concept at first. Afterwards, a description of design parameters for pistons of natural gas engines and a technical overview of piston bowls is given. Subsequent to the analysis of the different piston bowls, a new design approach is presented.

On the way to a climate-neutral mobility, synthetic fuels with their potential of CO2-neutral production are currently in the focus of internal combustion research. In this study, the C1-fuels methanol (MeOH), dimethyl carbonate (DMC), and methyl formate (MeFo) are tested as pure fuel mixtures and as blend components for gasoline. The study was performed on a single-cylinder engine in two configurations, thermodynamic and optical. As pure C1-fuels, the previously investigated DMC/MeFo mixture is compared with a mixture of MeOH/MeFo. DMC is replaced by MeOH because of its benefits regarding laminar flame speed, ignition limits and production costs. MeOH/MeFo offers favorable particle number (PN) emissions at a cooling water temperature of 40 °C and in high load operating points. However, a slight increase of NOx emissions related to DMC/MeFo was observed. Both mixtures show no sensitivity in PN emissions for rich combustions. This was also verified with help of the optical engine.

In order to fulfill future exhaust emission regulations, the variety of subsystems of internal combustion engines is progressively investigated and optimized in detail. The present article mainly focuses on studies of the flow field and the resulting discharge coefficients of the intake and exhaust valves and ports. In particular, the valves and ports influence the required work for the gas exchange process, as well as the cylinder charge and consequently highly impact the engine’s performance. For the evaluation of discharge coefficients of a modern combustion engine, a stationary flow test bench has been set up at the Chair of Internal Combustion Engines (LVK) of the Technical University of Munich (TUM). The setup is connected to the test bench’s charge air system, allowing the adjustment and control of the system pressure, as well as the pressure difference across the particular gas exchange valve.

Diesel engines are arguably the superior device in the ground transportation sector in terms of efficiency and reliability, but suffer from inferior emission performance due to the diffusive nature of diesel combustion. Great research efforts gradually reduced nitrogen oxide (NOX) and particulate matter (PM) emissions, but the PM-NOX trade-off remained to be a problem of major concern and was believed to be inevitable for a long time. In the process of engine development, the modification of fuel properties has lately gained great attention. In particular, the oxygenate fuel oxymethylene ether (OME) has proven potential to not only drastically reduce emissions, but possibly resolve the formerly inevitable trade-off completely.