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Polyoxymethylene dimethyl ethers (OME) are synthetic fuels, which offer the property of sustainability because the reactants of production base on hydrogen and carbon dioxide on the one hand, and the air pollution control in consequence of a soot-free combustion in a diesel engine on the other hand. High exhaust gas recirculation (EGR) rates are a promising measure for nitrogen oxide (NOx) reduction without increasing particle emissions because of the resolved soot-NOx trade-off. However, EGR rates towards stoichiometric combustion in OME operation reveals other trade-offs such as methane and formaldehyde emissions. To avoid these, a lean mixture with a combination of EGR and exhaust after-treatment with selective catalytic reduction (SCR) is useful. The limitation of urea dosing due to the light-off temperature of SCR systems requires heating measures.

The European Commission has released strict emission regulations for passenger cars in the past decade in order to improve air quality in cities and limit harmful emission exposure to humans. In the near future, even stricter regulations containing more realistic/demanding driving scenarios and covering more exhaust gas components are expected to be released. Passenger cars fueled with gasoline are one contributor to unhealthy air conditions, due to the fact that gasoline engines emit harmful air pollutants. One option to minimize harmful emissions would be to utilize specifically tailored, low emission synthetic fuels or fuel blends in internal combustion engines. Methyl formate and dimethyl carbonate are two promising candidates to replace or substitute gasoline, which in previous studies have proven to significantly decrease harmful pollutants.