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A new constant volume combustion chamber (CVCC) apparatus is presented that calculates the cetane number (CN) of fuels from their ignition delay by means of a primary reference fuel calibration. It offers the benefits of low fuel consumption, suitability for non-lubricating substances, accurate and fast measurements and a calibration by primary reference fuels (PRF). The injection system is derived from a modern common-rail passenger car engine. The apparatus is capable of fuel injection pressures up to 1200 bar and requires only 40 ml of the test fuel. The constant volume combustion chamber can be heated up to 1000 K and pressurized up to 50 bar. Sample selection is fully automated for independent operation and low levels of operator involvement. Capillary tubes employed in the sampling system can be heated to allow the measurement of highly viscous fuels.

On the way to a climate-neutral mobility, synthetic fuels with their potential of CO2-neutral production are currently in the focus of internal combustion research. In this study, the C1-fuels methanol (MeOH), dimethyl carbonate (DMC), and methyl formate (MeFo) are tested as pure fuel mixtures and as blend components for gasoline. The study was performed on a single-cylinder engine in two configurations, thermodynamic and optical. As pure C1-fuels, the previously investigated DMC/MeFo mixture is compared with a mixture of MeOH/MeFo. DMC is replaced by MeOH because of its benefits regarding laminar flame speed, ignition limits and production costs. MeOH/MeFo offers favorable particle number (PN) emissions at a cooling water temperature of 40 °C and in high load operating points. However, a slight increase of NOx emissions related to DMC/MeFo was observed. Both mixtures show no sensitivity in PN emissions for rich combustions. This was also verified with help of the optical engine.