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The objective draw by this project is to develop tools for Plug-in Hybrid Electric Vehicle (PHEV) design, energy analysis and energy management, with the aim of analyzing the effect of design, driving cycles, charging frequency and energy management on performance, fuel economy, range and battery life. A Chevrolet Equinox fueled by bio diesel B20 has been hybridized at the Center for Automotive Research (CAR), at The Ohio State University. The vehicle model has been developed in Matlab/Simulink environment, and validated based on laboratory and test. The PHEV battery pack has been modeled starting from Li-Ion batteries experimental data and then implemented into the simulator. In order to simulate “real world” scenarios, custom driving cycles/typical days were identified starting from average driving statistics and well-known cycles.