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To comply with the new regulations on particulate matter emissions, the manufacturers of light-duty as well as heavy-duty vehicles more commonly use diesel particulate filters (DPF). The regeneration of DPF depends to a significant extent on the properties of the soot stored. Within the Cluster of Excellence "Tailor-Made Fuels from Biomass (TMFB)" at RWTH Aachen University, the Institute for Combustion Engines carried out a detailed investigation program to explore the potential of future biofuel candidates for optimized combustion systems. The experiments for particulate measurements and analysis were conducted on a EURO 6-compliant High Efficiency Diesel Combustion System (HECS) with petroleum-based diesel fuel as reference and a today's commercial biofuel (i.e., FAME) as well as a potential future biomass-derived fuel candidate (i.e., 2-MTHF/DBE). Thermo gravimetric analyzer (TGA) was used in this study to evaluate the oxidative reactivity of the soot.

Fuel properties are always considered as one of the main factors to diesel engines concerning performance and emission discussions. There are still challenges for researchers to identify the most correlating and non-correlating fuel properties and their effects on engine behavior. Statistical analyses have been applied in this study to derive the most un-correlating properties. In parallel, sensitivity analysis was performed for the fuel properties as well as to the emission and performance of the engine. On one hand, two different analyses were implemented; one with consideration of both, non-aromatic and aromatic fuels, and the other were performed separately for each individual fuel group. The results offer a different influence on each type of analysis. Finally, by considering both methods, most common correlating and non-correlating properties have been derived.