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Gaseous fuel originated from natural gas (NG) has been affected by industrial fields thanks to its low emission feature. The excellent knock resistance of methane, a major component of NG, is another advantage in engine applications, but the composition of NG varies depending on the production region. Methane number (MN) has been widely used to evaluate the knock resistance of certain NG. However, the selection of a reliable knock-resisting index has not been settled because of several definitions of MN, and a new index called the propane knock index was recently proposed. Moreover, the proper index could change with types of gas engines. In this study, a rapid compression-and-expansion machine (RCEM) was prepared to reproduce in-cylinder conditions and combustion processes of a pre-chamber type medium-speed gas engine, and the knocking-like combustion was intentionally generated by setting compression pressure, ignition timing, and fuel density in the mixture to the proper level.