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Compression ignition engines are widely used for transport and energy generation due to their high efficiency and low fuel consumption. To minimize the environmental impact of this technology, the pollutant emissions levels at the exhaust are strictly regulated. To reduce the after-treatment needs, alternative strategies as the low temperature combustion (LTC) concepts are being investigated recently. The reactivity controlled compression ignition (RCCI) uses two fuels (direct- and port- injected) with different reactivity to control the in-cylinder mixture reactivity by adjusting the proportion of both fuels. In spite of the proportion of the port-injected fuel is typically higher than the direct-injected one, the characteristics of the latter play a main role on the combustion process. Use of gasoline for direct injection is attractive to retard the start of combustion and to improve the air-fuel mixing process.