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For real working-process simulations it is essential to know the caloric properties of the working fluid, such as the specific enthalpy and the real gas constant. When using standard-fuels there are established models which describe the caloric variables as functions of temperature, air/fuel-ratio and pressure. In each case, these models were developed for a certain fuel composition and their application to alternative fuels is limited or not valid at all. Thus, an approach is discussed, which is valid for any user-defined fuel. This work presents the formulations for the caloric modelling of burnt gas and fuel vapor, respectively. An algorithm is introduced that provides a very fast calculation of the chemical equilibrium condition of burnt gas. The influence of the equilibrium coefficients and the fuel composition on the chemical equilibrium composition is discussed.

Turbocharged SI-DI-engines in combination with a reduction of engine displacement (“Downsizing”) offer the possibility to remarkably reduce the overall fuel consumption. In charged mode it is possible to scavenge fresh unburnt air into the exhaust system if a positive slope during the overlap phase of the gas exchange occurs. The matching of the turbo system in SI-engines always causes a trade-off between low-end torque and high power output. The higher mass flow at low engine speeds of an engine using scavenging allows a partial solution of this trade-off. Thus, higher downsizing grades and fuel consumption reduction potential can be obtained. Through scavenging the global fuel to air ratio deviates from the local in-cylinder fuel to air ratio. It is possible to use a rich in-cylinder fuel to air ratio, whereas the global fuel to air ratio remains stochiometrical. This could be very beneficial to reduce the effect of catalytic aging on the one hand and engine knock on the other hand.