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There is a broad range of material choices for on-road and off-road exhaust systems. The final selection of the materials depends on the balance of engineering performance of the materials and the cost. Thermal-cycling resistance of exhaust materials is an extremely important criterion for the long-term durability and reliability performance of very high temperature exhaust components and systems. To optimize the thermal-cycling resistance and cost of those materials, a selection matrix must be established. Several material evaluation and selection matrices are already available, however, these are not sufficient to meet the industry needs. The current procedure of material selection is essentially based on the trial-and-error approach, which is not efficient in the current market environment. In this paper, a general rational approach for thermal-cycling resistance characterization and ranking is demonstrated.

Corrosion-fatigue (CF) and stress corrosion cracking (SCC) have long been recognized as the major degradation and failure mechanisms of engineering materials under combined mechanical loading and corrosive environments. How to model and characterize these failure phenomena and how to screen, rank, and select materials in corrosion-fatigue and stress corrosion cracking resistance is a significant challenge in the automotive industry and many engineering applications. In this paper, the mathematical structure of a superposition-theory based corrosion-fatigue model is investigated and possible closed-form and approximate solutions are sought. Based on the model and the associated solutions and test results, screening and ranking of the materials in fatigue, corrosion-fatigue are discussed.

Corrosion resistance is an extremely important technical issue for long-term durability and reliability performance of exhaust components and systems. Failure mechanisms, such as corrosion, fatigue, corrosion-fatigue and stress corrosion cracking, have long been recognized as the principal degradation and failure mechanisms of vehicle components and systems under combined mechanical and corrosive environmental conditions. The combination of fluid flow, introduced by components such as advanced injectors, and corrosive environment leads to corrosion-erosion failure mechanism. These failure mechanisms are strongly material, environment, and loading dependent. How to characterize, screen, rank and select the materials in corrosion resistance is a big challenge posed to materials scientists and engineers. In this paper, the common corrosion related failure mechanisms appearing in auto exhaust systems are reviewed first.