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Urea-SCR(selective catalytic reduction) system is widely used as a technology of NOx(Nitrogen Oxides) reduction from diesel engine exhaust gases. Emission regulations have becoming stricter all over the world, and high NOx reduction performance is necessary to meet the emission regulations. To get higher NOx reduction performance of the Urea-SCR system, it is important to understand detailed chemical reaction mechanisms of Urea-SCR catalysts. In this study, we focused on elucidation of the reaction mechanism of the Urea-SCR catalyst by numerical simulation approach. The chemical reaction models with detail chemical reactions were built for both Fe-catalyst and Cu-catalyst. Both of the catalytic reaction models can predict difference of the catalytic reaction performance between the Fe-catalyst and the Cu-catalyst. In addition, rate-determining reaction step of the Cu-catalyst was successfully identified by the numerical simulation results.

The new Diesel Particulate active Reduction (DPR) system was developed for a medium-duty commercial vehicle as a deNOx catalyst combined with the conventional DPR system to achieve the Japan Post New-Long-Term (JPNLT) emissions regulations. It consists of a catalyst converter named as the new DPR cleaner, a fuel dosing injector, NOx sensors, temperatures and pressure sensors. The new DPR cleaner was constructed from a Front Diesel Oxidation Catalyst (F-DOC), a catalyzed particulate Filter (Filter), and a Rear Diesel Oxidation Catalyst (R-DOC). A newly developed Hydrocarbon Selective Catalyst Reduction (HC-SCR) catalyst was employed for each catalyst aiming to reduce NOx emissions with diesel fuel supplied from the fuel dosing injector. While the total volume of the catalyst was increased, the compact and easy-to-install catalyst converter was realized through the optimization of the flow vector and flow distribution in it by means of Computational Fluid Dynamics (CFD) analysis.

A 2-LEG NOx Storage-Reduction (NSR) catalyst system is one of potential after-treatment technology to meet stringent NOx and PM emissions standards as Post New Long Term (Japanese 2009 regulation) and US'10. Concerning NOx reduction using NSR catalyst, a secondary fuel injection is necessary to make fuel-rich exhaust condition during the NOx reduction, and causes its fuel penalty. Since fuel injected in the high-temperature (∼250 degrees Celsius) exhaust instantly reacts with oxygen in common diesel exhaust, the proportion of fuel consumption to reduce the NOx stored on NSR catalyst is relatively small. A 2-LEG NSR catalyst system has the decreasing exhaust flow mechanism during NOx reduction, and the potential to improve the NOx reduction and fuel penalty. Therefore, this paper studies the 2-LEG NSR catalyst system. The after-treatment system consists of NSR catalysts, a secondary fuel injection system, flow controlled valves and a Catalyzed Diesel Particulate Filter (CDPF).

To reduce NOx and PM emissions in exhaust gas, after-treatment systems for low NOx emissions are being developed in combination with improvements of engine combustion. In recent years, the exhaust gas temperature has been dropping because of enhanced low-fuel consumption of the engine. Therefore, it is urgent to develop NOx reduction technologies that work at a low temperature under 200degC. Since NOx is reduced by reacting with ammonia supplied to the SCR catalyst, it is necessary to make the urea solution decompose into ammonia using the heat of the exhaust gas to supply sufficient ammonia to the SCR catalyst. However, both the decomposition reaction and hydrolysis reaction of the urea have insufficient exhaust heat, thus making it difficult for urea to decompose and hydrolyze to ammonia at a low temperature. To solve this problem, it focuses on forcibly decomposing the urea solution without depending on the exhaust gas temperature.