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This paper describes and compares different powertrain configurations for the retrofit of a heavy-duty Class 8 truck, powered by a 12.6 liters diesel engine. The engine is firstly equipped with an electrification-oriented organic Rankine cycle (ORC) system and then coupled to a traction electric machine into a hybrid powertrain. An electrification-oriented ORC system can produce enough energy to cover the ancillary loads, which in long-haul applications for freight transportation are quite demanding. Nevertheless, only powertrain hybridization can achieve significant improvements in the overall system efficiency. Both systems may thus be implemented in the same vehicle, but an efficiency improvement is guaranteed only if the system is carefully managed so as to reach a trade-off between the requirements and potential benefits of the ORC system and those of the hybrid powertrain.