Search Results

The European Particle Measurement Program (PMP) defines the current standard for measurement of Particle Number (PN) emissions from vehicles in Europe. This specifies a 50% count efficiency (D50) at 23 nm and a 90% count efficiency (D90) at 41 nm. Particulate emissions from Gasoline Direct Injection (GDI) engines have been widely studied, but usually only in the context of PMP or similar sampling procedures. There is increasing interest in the smallest particles - i.e. smaller than 23 nm - which can be emitted from vehicles. The literature suggest that by moving D50 to 10 nm, PN emissions from GDI engines might increase by between 35 and 50% but there remains a lot of uncertainty.

Forthcoming worldwide emissions regulations will start regulating ammonia emissions from light duty vehicles. At present, most light duty vehicles are powered by gasoline spark ignition engines. Sources of ammonia emission from such engines can be in-cylinder reactions (i.e. combustion) or downstream reactions across aftertreatment devices, particularly three-way catalysts. The latter has been known to be a major source of ammonia emissions from gasoline vehicles and has been extensively investigated. The former (combustion), less so, and thus is the subject of this work. A two-zone thermodynamic spark ignition engine model with a comprehensive chemical kinetics framework (C3MechV3.3 mechanism), after being validated against experimental ammonia emissions data, is used to study ammonia formation during combustion.