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The performance, life cycle cost, and safety of electric and hybrid electric vehicles (EVs and HEVs) depend strongly on their energy storage system. Advanced batteries such as lithium-ion (Li-ion) polymer batteries are quite viable options for storing energy in EVs and HEVs. In addition, thermal management is essential for achieving the desired performance and life cycle from a particular battery. Therefore, to design a thermal management system, a designer must study the thermal characteristics of batteries. The thermal characteristics that are needed include the surface temperature distribution, heat flux, and the heat generation from batteries under various charge/discharge profiles. Therefore, in the first part of the research, surface temperature distribution from a lithium-ion pouch cell (20Ah capacity) is studied under different discharge rates of 1C, 2C, 3C, and 4C.