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Emissions of Unburned Hydrocarbons (UHC) from diesel engines are a particular concern during the starting process, when after-treatment devices are typically below optimal operating temperatures. Drivability in the subsequent warm-up phase is also impaired by large cyclic fluctuations in mean effective pressure (MEP). This paper discusses in-cylinder wall temperature influence on unburned hydrocarbon emissions and combustion stability during the starting and warm-up process in an optical engine. A laser-induced phosphorescence technique is used for quantitative measurements of in-cylinder wall temperatures just prior to start of injection (SOI), which are correlated to engine out UHC emission mole fractions and combustion phasing during starting sequences over a range of charge densities, at a fixed fueling rate. Squish zone cylinder wall temperature shows significant influence on engine out UHC emissions during the warm-up process.

In order to further understand the sequence of events leading to stochastic preignition in a spark-ignition engine, a methodology previously developed by the authors was used to evaluate the propensity of a wide range of fuels to establishing propagating flames under conditions representative of those at which stochastic preignition (SPI) occurs. The fuel matrix included single component hydrocarbons, binary mixtures, and real fuel blends. The propensity of each fuel to establish a flame was correlated to multiple fuel properties and shown to exhibit consistent blending behaviors. No single parameter strongly predicted a fuel’s propensity to establish a flame, while multiple reactivity-based parameters exhibited moderate correlation. A two-stage model of the flame establishment process was developed to interpret and explain these results.