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Faced with the need to reduce greenhouse gas emissions, diesel engines present the advantage of having low CO₂ emission levels compared to spark-ignited engines. Nevertheless, diesel engines still suffer from the fact that they emit pollutants and, particularly nitrogen oxides (NOx) and particulates (PM). One of the most promising ways to meet this challenge is to reduce the compression ratio (CR). However a current limitation in reducing the diesel CR is cold start requirements. In this context, the fuel characteristics such as the cetane number, which represents ignition, and volatility could impact cold start. That is why a matrix of 8 fuels was tested. The cetane number ranges from 47.3 to 70.9 and the volatility, represented by the temperature necessary to distillate 5% of the product (T5%), ranges from 173 to 198°C. The engine tests were carried out at -25°C, on a common rail 4-cylinder diesel engine.

Due to the increasing use of Fatty Acid Methyl Esters (FAME) in diesel fuel blends and the sensitivity of the latest Diesel engine technology (higher pressures and temperatures), a reliable method for predicting the thermal stability of biodiesel fuels is required. A laboratory bench test, called MicroCoking test, which usually qualifies engine oils, has been modified in order to be used for biodiesel blended fuels. Experimental conditions, and especially temperature range, were optimized in order to lead to a sensitive and discriminating method to qualify pure biodiesel fuels and Diesel blends containing FAME.

Facing more and more stringent regulations, new solutions are developed to decrease pollutant emissions. One of them have shown promising and relevant results. It consists of the use of ethanol as a blending component for diesel fuel Nevertheless, the addition of ethanol to Diesel fuel affects some key properties such as the flash point. Consequently, Diesel blends containing ethanol become highly flammable at a temperature around ambient temperature. This study proposes to improve the formulation of ethanol based diesel fuel in order to avoid flash point drawbacks. First, a focus on physical and chemical properties is done for ethanol based diesel fuels with and without flash point improvement. Second, blends are tested on a passenger car diesel engine, under a wide operating range conditions from low load low speed up to maximum power. The main advantage of the ethanol based fuels generate low smoke level, that allows using higher EGR rate, thus leading to an important NOx decrease.

This work studies the potential of ethanol-Biodiesel-Diesel fuel blends in both conventional Diesel and HCCI combustion modes. First, ethanol based fuels were tested on a modern commercial multi-cylinder DI diesel engine. The aim of this phase was to assess how such fuels affect Diesel engine performances and emissions. These results indicate that low levels of PM and NOx emissions, with a contained fuel consumption penalty and with an acceptable noise level, are achievable when the Diesel-ethanol blends are used in combination with an optimized combustion control. Moreover, experiments with ethanol based blends were performed using a single cylinder engine, running under both early injection HCCI and Diesel combustion modes. Compared to a conventional fuel, these blends allow increasing the HCCI operating range and also lead to higher maximum power output in conventional Diesel combustion.

The use of Diesel engines has strongly increased during the last years and now represents 30% of the sales in Europe and up to 50% of the number of cars in circulation for some countries. This success is linked not only to the economical aspect of the use of such vehicles, but also to the recent technological improvements of these engines. The new technical solutions (high pressure direct injection, turbocharging…) have indeed allowed the increase of these engine performances while decreasing their fuel consumption, pollutant emissions and noise level. From an environmental point of view, Diesel engines are nevertheless penalized by their particulate and NOx emissions. The study and the treatment of the particulate, highly criticized for their potential impact on health, are the subject of numerous works of characterization and developments. PSA Peugeot-Citroën has recently launched its particulate filter technology on several types of vehicles.