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With regulatory standards for diesel engine emissions becoming stricter worldwide, integrated catalytic systems are becoming increasingly necessary. One of the better approaches is to use an after-treatment system consisting of a diesel oxidation catalyst (DOC), a catalyzed diesel particulate filter (CDPF), and a selective catalytic reduction (SCR), but many factors can affect how well this system works. This study investigates the effects of DOC and CDPF catalyst composition on emissions characteristics for DOC + CDPF + SCR systems by collecting reactor and engine data. The reactor results show that the light-off temperatures (T50) of CO and C3H6 increase with the growth of Pt:Pd ratio while the T50 of NO degrades. An engine dynamometer test was conducted on a light-duty diesel engine equipped with DOC + CDPF + SCR. The results show light-off curves of CO and THC that are smoother than the reactor data.

To meet the increasingly stringent nitrogen oxides (NOx) emission regulations of diesel engines, the selective catalytic reduction (SCR) of NOx with ammonia (NH3) has become the current mainstream technical route. Experiments in the present study included the performance of Cu-Beta catalyst and Cu-CHA catalyst before and after hydrothermal aging, and the effects of Cu content, feed gas space velocity (GHSV), NH3/NOx ratio, and sulfur poisoning on the performance of Cu-CHA catalyst. In the low temperature range (T≤250 °C), the T50 and T90 of Cu-Beta catalyst are 139 °C and 165 °C, respectively, while those of Cu-CHA catalyst are 150 °C and 183 °C, respectively. In the high temperature range (T>400 °C), the NOx conversion of Cu-CHA catalyst is generally higher than that of Cu-Beta catalyst. The temperature window of Cu-Beta catalyst is 154 to 514 °C, while that of Cu-CHA catalyst is 168 to 522 °C. Cu-CHA catalyst exhibits better catalytic activity at medium and high temperatures.

The catalyzed diesel particulate filter with Pt and Pd noble metals as the main loaded active components are widely used in the field of automobile engines, but the high cost makes it face huge challenges. Rare earth element doping can improve the soot oxidation performance of the catalyzed diesel particulate filter and provide a new way to reduce its cost. In this paper, thermogravimetric tests and chemical reaction kinetic calculations were used to explore the effect of Pt-Pd catalysts doped Ce, and La rare earth elements on the oxidation properties of soot. The results shown that, among Pt-Pd-5%Ce, Pt-Pd-5%La, and Pt-Pd-5%Ce-5%La catalysts, Pt-Pd-5%La catalyst has the highest soot conversion, the highest low-temperature oxidation speed, and the activation energy is the smallest. Compared with soot, this catalyst reduced T10 and T20 by 82% and 26%, respectively, meaning the catalytic activity of Pt-Pd-5%La catalyst was the best.