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The increased severity and prevalence of insoluble deposits formed on fuel injectors in gasoline direct injection (GDI) engines precipitates negative environmental, economic and healthcare impacts. A necessary step in mitigating deposits is to unravel the molecular compositions of these complex layered materials. But very little molecular data has been acquired. Mass spectrometry shows promise but most techniques require the use of solvents, making them unsuited for analyzing insoluble deposits. Here, we apply the high mass-resolving power and in-situ analysis capabilities of 3D OrbitrapTM secondary ion mass spectrometry (3D OrbiSIMS) to characterize deposits formed on the external tip and internal needle from a GDI injector. This is the first application of the technique to study internal GDI deposits. Polycyclic aromatic hydrocarbons (PAHs) are present up to higher maximum masses in the external deposit.

Over the last decade, there has been an impetus in the automobile industry to develop new diesel injector systems, driven by a desire to reduce fuel consumption and proscribed by the requirement to fulfil legislation emissions. The modern common-rail diesel injector system has been developed by the industry to fulfil these aspirations, designed with ever-higher tolerances and pressures, which have led to concomitant increases in fuel temperatures after compression with reports of fuel temperatures of ~150°C at 1500-2500 bar. This engineering solution in combination with the introduction of Ultra Low Sulphur diesel fuel (ULSD) has been found to be highly sensitive to deposit formation both external injector deposits (EDID) and internal (IDID). The deposits have caused concerns for customers with poor spray patterns misfiring injector malfunction and failure, producing increased fuel consumption and emissions.

There have been reports of internal injector deposits causing problems in diesel engines in the field from 2008. Such problems manifest themselves as rough idling, power loss, high emissions, high-pressure fuel pump wear, injector sticking, internal component corrosion and engine failure. These reports coincided with the use of common rail diesel injection systems and of ultra-low sulphur fuels introduced because of emission regulation demands. The injection systems have design features that are more conducive or susceptible to deposit formation such as severe high temperature and pressure operating conditions, the tolerances of critical parts, and lower force internal component actuation. The changes to fuels have also affected the fuels ability to solubilise these deposits. The deposits formed manifest themselves in complex form in the field, often being mixtures of inorganic and organic compounds.

Exhaust Gas Recirculation (EGR) is employed in diesel engines to reduce engine-out NOx. Carbon-containing deposits form in the EGR systems of modern diesel engines as the particulate matter, hydrocarbons and other entrained species deposit from the exhaust gas flow as it cools. Much work has been done by Original Equipment Manufacturers (OEMs) to reduce deposits and mitigate their effects by optimized dimensioning of EGR coolers and valves, introduction of EGR cooler bypass for use in the most sensitive cold conditions and experimenting with oxidation catalysts upstream of the EGR system. Nevertheless, deposits forming in the high-pressure Exhaust Gas Recirculation (HP-EGR) systems of modern diesel engines can sometimes lead to a number of problems including emissions and fuel consumption deterioration, poor performance and drivability, as well as breakdowns. An engine test method has been developed to enable the impact of fuel on deposits in the HP-EGR system to be studied.

Developed by Rudolph Diesel in the 1890s, the diesel powertrain is used in many applications worldwide. For significant time the engine fuel source for these engines was petroleum diesel, until new legislation regarding emission reduction and smog mitigation saw the introduction of petroleum diesel and biodiesel (Fatty acid methyl ester; FAME) blends in the early 2000s. Since then there have been many instances of filters in diesel powertrains across heavy, light and off-road platforms becoming blocked with unidentified material, for example in the United States, Northern Europe and Scandinavia. Filters are designed to remove contaminants from the fuel system and as the filter becomes plugged it restricts the fuel flow resulting in loss of engine power and eventual breakdown. Understanding The nature of the material responsible for such blockages is clearly important to the industry and has been the subject of many studies.

Exhaust Gas Recirculation (EGR) is employed in diesel engines to reduce engine-out NOx emissions. Despite the concerted design efforts of manufacturers, high-pressure Exhaust Gas Recirculation (HP-EGR) systems can be susceptible to fouling as the particulate matter, hydrocarbons and other entrained species deposit from the exhaust gas flow as it cools on its passage through the EGR system. Such deposits can lead to a number of problems including deterioration of emissions, fuel efficiency, performance and drivability, as well as breakdowns. The development of an engine test method to enable the study of the impact of fuel on deposits in the HP-EGR system was reported in 2020. In the test, a 4-cylinder light-duty diesel engine of 1.6L displacement runs at conditions conducive to EGR deposit formation over 24 hours and the impact of fuels on deposit formation is determined through weighing of the EGR system components before and after the test.