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This study has been computationally investigated how the DME autoignition reactivity is affected by EGR and intake-pressure boost over various engine speed. CHEMKIN-PRO was used as a solver and chemical-kinetics mechanism for DME was utilized from Curran's model. We examined first the influence of EGR addition on autoignition reactivity using contribution matrix. Investigations concentrate on the HCCI combustion of DME at wide ranges of engine speeds and intake-pressure boost with EGR rates and their effects on variations of autoignition timings, combustion durations in two-stage combustion process in-detail including reaction rates of dominant reactions involved in autoignition process. The results show that EGR addition increases the combustion duration by lowering reaction rates.