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Urea Decomposition at Low Temperature in SCR Systems for Diesel Engines

2014-10-13
2014-01-2808
Selective catalytic reduction (SCR) has been demonstrated as one of the most promising technologies to reduce NOx emissions from heavy-duty diesel engines. To meet the Euro VI regulations, the SCR system should achieve high NOx reduction efficiency even at low temperature. In the SCR system, NH3 is usually supplied by the injection of urea water solution (UWS), therefore it is important to improve the evaporation and decomposition efficiency of UWS at low temperature and minimize urea deposits. In this study, the UWS spray, urea decomposition, and the UWS impingement on pipe wall at low temperature were investigated based on an engine test bench and computational fluid dynamics (CFD) code. The decomposition of urea and deposits was analyzed using thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC) and fourier transform infrared spectroscopy (FTIR).
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