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Biogas is a gas resulting from biomass, with a volumetric content of methane (CH4) usually ranging between 50% and 70%, and carbon dioxide (CO2) content between 30% and 50%; it can also contain hydrogen (H2) depending on the feedstock. Biogas is generally used to generate electricity or produce heat in cogeneration system. Due to its good efficiency through the rapid combustion and lean air-fuel mixture, Homogeneous Charge Compression Ignition (HCCI) engine is a good candidate for such application. However, the engine load must be kept low to contain the high-pressure gradients caused by the simultaneous premixed combustion of the entire in-cylinder charge. The homogenous charge promotes low particulate emissions, and the dilution helps in containing maximum in-cylinder temperature, hence reducing nitrogen oxide emissions. However, HC and CO levels are in general higher than in SI combustion.