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Biogas is a gas resulting from biomass, with a volumetric content of methane (CH4) usually ranging between 50% and 70%, and carbon dioxide (CO2) content between 30% and 50%; it can also contain hydrogen (H2) depending on the feedstock. Biogas is generally used to generate electricity or produce heat in cogeneration system. Due to its good efficiency through the rapid combustion and lean air-fuel mixture, Homogeneous Charge Compression Ignition (HCCI) engine is a good candidate for such application. However, the engine load must be kept low to contain the high-pressure gradients caused by the simultaneous premixed combustion of the entire in-cylinder charge. The homogenous charge promotes low particulate emissions, and the dilution helps in containing maximum in-cylinder temperature, hence reducing nitrogen oxide emissions. However, HC and CO levels are in general higher than in SI combustion.

While the optimization of the internal combustion engine (ICE) remains a very important topic, alternative fuels are also expected to play a significant role in the reduction of CO2 emissions. High energy densities and handling ease are their main advantages amongst other energy carriers. Ammonia (NH3) additionally contains no carbon and has a worldwide existing transport and storage infrastructure. It could be produced directly from renewable electricity, water and air, and is thus currently considered as a smart energy carrier and combustion fuel. However, ammonia presents a low combustion intensity and the risk of elevated nitrogen-based emissions, thus rendering in-depth investigation of its suitability as an ICE fuel necessary. In the present study, a recent single-cylinder spark-ignition engine is fueled with gaseous ammonia/hydrogen/air mixtures at various hydrogen fractions, equivalence ratios and intake pressures.

Ammonia is now recognized as a very serious asset in the context of the hydrogen energy economy, thanks to its non-carbon nature, competitive energy density and very mature production, storage and transport processes. If produced from renewable sources, its use as a direct combustion fuel could participate to the flexibility in the power sector as well as help mitigating fossil fuel use in certain sectors, such as long-haul shipping. However, ammonia presents unfavorable combustion properties, requiring further investigation of its combustion characteristics in practical systems. In the present study, a modern single-cylinder spark-ignition engine is fueled with gaseous ammonia/air mixtures at various equivalence ratios and intake pressures. The results are compared with methane/air and previous ammonia/hydrogen/air measurements, where hydrogen is used as combustion promoter. In-cylinder pressure and exhaust concentrations of selected species are measured and analyzed.

In the search for zero-carbon emissions and energy supply security, hydrogen is one of the fuels considered for internal combustion engines. The state-of-the-art studies show that a good strategy to mitigate NOx emissions in hydrogen-fueled spark-ignition engines (H2ICE) is burning ultra-lean hydrogen-air mixtures in current diesel architectures, due to their capability of standing high in-cylinder pressures. However, it is well-known that decreasing equivalence ratio leads to higher engine instability and greater cycle-to-cycle variations (CCVs). Nevertheless, hydrogen flames, especially at low equivalence ratios and high pressures, present thermodiffusive instabilities that speed up combustion, changing significantly the flame development and possibly its variability. This work evaluates the hydrogen combustion and their CCVs in two single-cylinder diesel baseline H2ICEs (light-duty and medium-duty) and their influence on performance parameters.