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Although in the latest years the use of compression ignition engines has been a thread of discussion in the automotive field, it is possible to affirm that it still will be a fundamental producer of mechanical power in other sectors, such as naval and off-road applications. However, the necessity of reducing emissions requires to keep on studying new solutions for this kind of engine. Dual fuel combustion concept with methane has demonstrated to be effective in preserving the performance of the original engine and reducing soot, but issues related to the low flame speed forced researcher to find an alternative fuel at low impact of CO2. Hydrogen, thanks to its chemical and physical properties, can be a perfect candidate to ensure a good level of combustion efficiency; however, this is possible only with a proper management of the in-cylinder mixture ignition by means of a pilot injection, preventing uncontrolled autoignition events as well.