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Two premixed compression ignition modes for low octane gasoline are numerically investigated. The multiple premixed compression ignition (MPCI) mode is featured with a sequence of “spray- combustion- spray- combustion”, while the partially premixed compression ignition (PPCI) mode is a sequence of “spray- spray- combustion”. This paper compares the combustion process of the two modes using multi-dimensional CFD code, KIVA-3v, which can perform chemical reaction calculations for different fuels by a discrete multiple component (DMC) method. The fuel used for simulation consists of 58.5% i-C8H18 and 41.5% n-C7H16 in volume, and has the same RON and similar physical properties to straight-run naphtha used in the experiment. The engine operating condition is fixed at a 1600rpm and 0.7 MPa IMEP. The injection strategies for these two modes are different. All of the parameters in the simulation come from the single cylinder engine experiments.