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The work reported in this paper contributes to understanding the effects of ethanol/gasoline ratio on mixture formation and cooling effect which are crucial in the development of EDI+GPI engine. The spray simulations were carried out using a commercial CFD code. The model was verified by comparing the numerical and experimental results of spray shapes in a constant volume chamber and cylinder pressure in an EDI+GPI research engine. The verified model was used to investigate the fuel vaporization and mixture formation of the EDI+GPI research engine. The effect of the ethanol/gasoline ratio on charge cooling has been studied. Compared with GPI only, EDI+GPI demonstrated stronger effect on charge cooling by decreased in-cylinder temperature. However, the cooling effect was limited by the low evaporation rate of the ethanol fuel due to its lower saturation vapour pressure than gasoline's in low temperature conditions.