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Recent work has demonstrated the potential of gasoline-like fuels to reduce NOX and particulates emissions when used in diesel engines. Indeed, fuels highly resistant to auto-ignition provide more time for fuel and air mixing prior to the combustion and therefore a more homogeneous combustion. Nevertheless, major issues still need to be addressed, particularly regarding UHC and CO emissions at low load and particulate/noise combustion trade-off at high load. The purpose of this study is to investigate how an existing modern diesel engine could be operated with low-cetane fuels and define the most appropriate Cetane Number (CN) to reduce engine-out emissions. With this regard, a selection of naphtha and gasoline blends, ranging from CN30/RON 57 to CN35/RON 41 was investigated on a Euro 5, 1.6L four-cylinder engine. Results were compared to the conventional diesel running mode using a minimum NOX level oriented calibration, both in steady state and transient conditions.