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In this paper, the formaldehyde emissions from three different types of homogenous charge compression ignition (HCCI) engines are quantified for a range of fuels by means of Fourier Transform Infra Red (FTIR) spectroscopic analysis. The engines types are differentiated in the way the charge is prepared. The characterized engines are; the conventional port fuel injected one, a type that traps residuals by means of a Negative Valve Overlap (NVO) and finally a Direct Injected (DI) one. Fuels ranging from pure n-heptane to iso-octane via diesel, gasoline, PRF80, methanol and ethanol were characterized. Generally, the amount of formaldehyde found in the exhaust was decreasing with decreasing air/fuel ratio, advanced timing and increasing cycle temperature. It was found that increasing the source of formaldehyde i.e. the ratio of heat released in the cool-flame, brought on higher exhaust contents of formaldehyde.

Simultaneous OH- and formaldehyde planar-LIF measurements have been performed in an optical engine using two laser sources working on 283 and 355 nm, respectively. The engine used for the measurements was a car Diesel engine converted to single-cylinder operation and modified for optical access. The fuel, n-heptane, was injected by a direct injection common rail system and the engine was also fitted with an EGR system. The engine was operated in both HCCI mode and Diesel mode. Due to the low load, the Diesel mode resulted in low-temperature Diesel combustion and because of limitations in maximum pressure and maximum rate of pressure increase of the optical engine, the Diesel mode was run at a higher EGR percentage than the HCCI mode to slow down the combustion. A third mode, pilot combustion, was also investigated. This pilot combustion is created by an injection at 30 CAD before TDC followed by a second injection just before TDC.

A naturally aspirated in-line six-cylinder 2.9-litre Volvo engine is operated in Homogeneous Charge Compression Ignition (HCCI) mode, using camshafts with low lift and short duration generating negative valve overlap. Standard port fuel injection is used and pistons and cylinder head are unchanged from the automotive application. HCCI through negative valve overlap is recognized as one of the possible implementation strategies of HCCI closest to production. It is important to gain knowledge of the constraints and limits on the possible operating region. In this work, the emphasis is on investigating how cycle-to-cycle and cylinder-to-cylinder deviations limit the operating region, how these effects change in different parts of the operating region and how they can be controlled. At low load the cycle-to-cycle phenomena cause periodic behavior in combustion timing; together with cylinder deviations this is found responsible for decreasing the operating regime.

Simultaneous OH- and formaldehyde planar-LIF measurements have been performed in an optical engine using two laser sources working on 283 and 355 nm, respectively. The measurements were performed in a light duty Diesel engine, using n-heptane as fuel, converted to single-cylinder operation and modified for optical access. It was also equipped with a direct injection common rail system as well as an EGR system. The engine was operated in both HCCI mode, using a single fuel injection, and UNIBUS (Uniform Bulky Combustion System) mode, using two injections of fuel with one of the injections at 50 CAD before TDC and the other one just before TDC. The OH and formaldehyde LIF images were compared with the heat-release calculated from the pressure-traces. Analyses of the emissions, for example NOx and HC, were also performed for the different operating conditions.