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Technical Paper

Effect of Substituted Phenol Fuel Additives on Ignition Delay of a Toluene Reference Fuel

2022-03-29
2022-01-0516
Aromatics have long been used in pump-grade gasoline to inhibit engine knock and enhance a fuel’s octane number, therefore this study focuses on how the addition of aromatics at 2% by mole affects the ignition characteristics of a Toluene Reference Fuel (TRF). The additives investigated in this study are the substituted phenols p-cresol and 2,6-xylenol. In addition to fuel composition, exhaust gas recirculation dilution can be used to lower the combustion temperature and consequently lengthen the ignition delay time of a given fuel-air mixture. This study replicated exhaust gas recirculation dilution by using N2, as it was inert and did not interfere with reactions between the fuel and oxidizer. Determination of whether the similar structures of p-cresol and 2,6-xylenol result in different autoignition inhibiting characteristics was performed on a rapid compression machine.
Technical Paper

A Qualitative Comparison of the Macroscopic Spray Characteristics of Gasoline Mixtures and their Multi-Component Surrogates Using a Rapid Compression Machine

2021-04-06
2021-01-0558
Rapid Compression Machines (RCM) offer the ability to easily change the compression ratio and the pressure/mixture composition/temperature to gather ignition delay data at various engine relevant conditions. Therefore, RCMs with optical access to the combustion chamber can provide an effective way to analyze macroscopic spray characteristics needed to understand the spray injection process and for spray model development, validation and calibration at conditions that are suitable for engines. Fuel surrogates can help control fuel parameters, develop models for spray and combustion, and perform laser diagnostics with known fluorescence characteristics. This study quantifies and evaluates the macroscopic spray characteristics of multicomponent gasoline surrogates in comparison to their gasoline counterparts, under gasoline direct injection (GDI) engine conditions.
Technical Paper

A Rapid Compression Machine Study on Ignition Delay Times of Gasoline Mixtures and their Multicomponent Surrogate Fuels under Diluted and Undiluted Conditions

2021-04-06
2021-01-0554
In this work autoignition delay times of two multi-component surrogates (high and low RON) were experimentally compared with their target full blend gasoline fuels. The study was conducted in a rapid compression machine (RCM) test facility and a direct test chamber (DTC) charge preparation approach was used for mixture preparation. Experiments were carried over the temperature range of 650K-900K and at 10 bar and 20 bar compressed pressure conditions for equivalence ratios of (Φ =) 0.6-1.3. Dilution in the reactant mixture was varied from 0% to 30% CO2 (by mass), with the O2:N2 mole ratio fixed at 1:3.76. This dilution strategy emulates exhaust gas recirculation (EGR) substitution in spark ignition (SI) engines. The multicomponent surrogate captured the reactivity trends of the gasoline-air mixtures reasonably well in comparison to the single component (iso-octane) surrogate.
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