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Technical Paper

Thermally Durable Zeolite Based SCR Catalysts for Controlling NOx Emissions in Diesel Exhaust to Meet BS VI Norms

2019-01-09
2019-26-0130
From the recent past, automotive exhaust emission management strategies has been progressing towards an alternative for vanadia based selective catalytic reduction (V-SCR) of NOx in diesel powered vehicles. Some of the major inadequacies of existing V-SCR technology were as follows: poor thermal endurance (deteriorates at 550°-600°C), volatilization of harmful vanadium into environment and inadequate NO2 conversion. Metal incorporated zeolite systems, (the metals being preferably selected from transition metal elements), has gained momentum for commercial DeNOx applications. However, the major challenge with this zeolite SCR (Z-SCR) was its low thermal/hydrothermal stability. In the current study, it has been attempted to overcome this by various zeolites and metals combinations. Various combinations of metallic Z-SCR were extensively studied for their low and high temperature activities.
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