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The worldwide introduction of new emission standards and new, more encompassing, legislating cycles have led to a need to increase both a selective catalytic reduction (SCR) system’s capacity and conversion efficiency. To this end, it is important for an SCR system to operate to the extremes of its temperature range which in many systems is currently limited by the temperature at which diesel exhaust fluid (DEF) can easily decompose without the formation of deposits. This paper analyses a new system for low-temperature ammonia provision to the SCR reaction. Ammonia Creation and Conversion Technology (ACCT) uses pressure controlled thermal decomposition of DEF followed by re-formation to form a fluid with greater volatility and the same ammonia density as DEF conforming to ISO 22241. A dosing strategy can then be employed where any combination of DEF or ACCT solution can be used to provide ammonia as a reductant over the whole activity temperature range of a catalyst.