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Global warming driven by “greenhouse gas” emissions is an increasingly serious concern of both the public and legislators. A potentially potent way to reduce these emissions and conserve fossil fuel resources is to use n-butanol, iso-butanol or octanol (2-ethylhexanol) from renewable sources as alternative fuels in diesel engines. The effects of adding these substances to diesel fuel were therefore tested in a single-cylinder heavy duty diesel engine operated using factory settings. These alcohols have better calorific values, flash points, lubricity, cetane numbers and solubility in diesel than shorter-chain alcohols. However, they have lower cetane numbers than diesel, so either hydrotreated vegetable oil (HVO) or Di-tertiary-butyl peroxide (DTBP) was added to the diesel-alcohol mixtures to generate blends with the same Cetane Number (CN) as diesel.