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Air source heat pumps as the heating system for full electric vehicles are drawing more and more attention in recent years. Despite the high energy efficiency, frost accumulation on the heat pump evaporator is one of the major challenges associated with air source heat pumps. The evaporator needs to be actively defrosted periodically and heat pump heating will be interrupted during defrosting process. Proper defrost control is needed to obtain high average heat pump energy efficiency. In this paper, a new method for generating air source heat pump defrost control policy using reinforcement learning is introduced. This model-free method has several advantages. It can automatically generate optimal defrost control policy instead of requiring manually determination of the control policy parameters and logics.