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In this paper, the influence of sulfur and ash fraction of lubricating oil on particle emissions was investigated via experimental works. Especially, we focus on the characterizations like size distribution, morphology and element composition in diesel particles. All of the research was done on a two-cylinder diesel engine under different load conditions. Five kinds of lubricating oils with different levels of sulfur and ash fraction were used in this study, among which a kind of 5W-30 (ACEA, C1) oil was used as baseline oil. Diesel primary particles were collected by thermophoretic system, and analyzed by transmission electron microscopy and energy dispersive X-ray spectrum technique, respectively. Conclusions drawn from the experiments indicate that the sulfur and ash change the primary particle emissions directly.

In this study, the effect of volatile fractions from engine lubricating oil on diesel particle emissions were studied experimentally. One commercial CF lubricating oil was used and distilled to subtract the different volatile fractions with boiling temperature of 220 °C, 260 °C and 300 °C, respectively. Oils derived from this distillation process were applied as the lubricating oil and following engine experiments were conducted. Diesel primary particles were sampled with a costume designed thermophoretic system. A fast response particulate spectrum equipment was employed to study the size distribution and number concentration of particles in the exhaust. Transmission electron microscopy was used to characterize the size distribution of the primary diesel particles relates to different oil volatile fractions.

In this paper, the influences of lubricating base oils on diesel particles morphology and nanostructure were investigated. Four different lubricating base oils were blended in diesel at a mass ratio of 0.5% and 1.0% for combustion. Exhaust particle samples generated by a four-cylinder, four-stroke direct injection engine when employing neat diesel and four base oil dosed mixtures as the fuel were collected and compared. Primary particle diameter distributions and particle nanostructure were compared and analyzed by a High-Resolution Transmission Electron Microscope (HRTEM). Conclusions drawn from the experiments indicated that the primary particles diameter ranges from 5 nm to 70 nm and the distribution conformed to typical Gaussian distribution. Base oil II, III, IV increased the primary particles diameter, while particles from base oil I exhibited smaller size than that from neat diesel.