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Ethyl tertiary butyl ether (ETBE) has been used as a high octane blending component since the early 1990's. However the strong interest in renewable energy has led to a dramatic increase in its use. This has also resulted in a substantial number of technical studies being carried out around the world to assess its performance with respect to vehicle performance, distribution system compatibility, environmental impact and toxicology. The purpose of this paper is to provide a comprehensive, up to date review of these data. Particular focus will be given to its positive impact on CO2 emissions.