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In-cylinder thermochemical fuel reforming (TFR) in spark ignition natural gas engine was developed to reveal that thermochemical fuel reforming could increase H2 and CO concentration in reformed gas, leading to an increase of thermal efficiency and engine performance. Moreover, ethanol enrichment has been proved to have great potential to optimize TFR performance. In order to explain TFR phenomenon chemically, methane oxidation experiments were conducted in a laminar flow reactor with addition of ethanol and methanol at equivalent ratios of 1.5, 1.7, 1.9 and 2.1 from 948K to 1098K at atmospheric pressure. Experimental results showed that methanol have great ability to facilitate the oxidation of methane than that of ethanol. Meanwhile, the degree of methane conversion became more significantly as the equivalent ratio increased. Kinetic analysis of oxidation of methane with alcohol enrichment in a plug flow model was also conducted in this study.