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In this study, a fully optically accessible single-cylinder research engine is the basis for the visualization and generation of extensive knowledge about the in-cylinder processes of mixture formation, ignition and combustion of oxygenated synthetic fuels. Previous measurements in an all-metal engine showed promising results by using a mixture of dimethyl carbonate and methyl formate as a fuel substitute in a DISI-engine. Lower THC and NOx emissions were observed along with a low PN-value, implying low-soot combustion. The flame luminosity transmitted via an optical piston was split in the optical path to simultaneously record the natural flame luminosity with an RGB high-speed camera. The second channel consisted of OH*-chemiluminescence recording, isolated by a bandpass filter via an intensified monochrome high-speed camera.

On the way to a climate-neutral mobility, synthetic fuels with their potential of CO2-neutral production are currently in the focus of internal combustion research. In this study, the C1-fuels methanol (MeOH), dimethyl carbonate (DMC), and methyl formate (MeFo) are tested as pure fuel mixtures and as blend components for gasoline. The study was performed on a single-cylinder engine in two configurations, thermodynamic and optical. As pure C1-fuels, the previously investigated DMC/MeFo mixture is compared with a mixture of MeOH/MeFo. DMC is replaced by MeOH because of its benefits regarding laminar flame speed, ignition limits and production costs. MeOH/MeFo offers favorable particle number (PN) emissions at a cooling water temperature of 40 °C and in high load operating points. However, a slight increase of NOx emissions related to DMC/MeFo was observed. Both mixtures show no sensitivity in PN emissions for rich combustions. This was also verified with help of the optical engine.