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A Durable and Efficient Cu Zeolite based SCR Catalyst for Cold Start and High Temperature DeNOx Applications

2021-09-22
2021-26-0190
Typical diesel engine-out emissions consist of hydrocarbons (HC), carbon monoxide (CO), particulate matter (PM) & oxides of nitrogen (NOx). The HC and CO emissions are oxidized by a diesel oxidation catalyst (DOC), placed upstream, closer to the exhaust manifold. The DOC is often followed by a diesel particulate filter (DPF), which entraps and combusts PM. The NOx is often controlled by a selective catalytic reduction (SCR) catalyst. An SCR catalyst commonly uses NH3 to reduce the NOx to N2. Vanadium-based SCR catalysts have been widely used for many years. More recently, Cu-Zeolite based SCR (CuZ-SCR) is gaining much attention primarily due to the potential environmental hazards of vanadium and a wider temperature window of effective operation. The SCR reaction is facilitated by the presence of NO2 at lower exhaust gas temperatures by means of the so-called “fast” reaction. However, this is only advantageous up to about 300°C.
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