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Isobaric combustion has been proven a promising strategy for high efficiency as well as low nitrogen oxides emissions, particularly in heavy-duty Diesel engines. Previous single-cylinder research engine experiments have, however, shown high soot levels when operating isobaric combustion. The combustion itself and the emissions formation with this combustion mode are not well understood due to the complexity of multiple injections strategy. Therefore, experiments with an equivalent heavy-duty Diesel optical engine were performed in this study. Three different cases were compared, an isochoric heat release case and two isobaric heat release cases. One of the isobaric cases was boosted to reach the maximum in-cylinder pressure of the isochoric one. The second isobaric case kept the same boost levels as the isochoric case. Results showed that in the isobaric cases, liquid fuel was injected into burning gases. This resulted in shorter ignition delays and thus a poor mixing level.