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A numerical simulation was performed to investigate the pilot ignited natural gas combustion process in a direct injection natural gas engine. Various mixture distribution characteristics were compared in terms of the evolution of mixture equivalent ratio distributions and mixture concentration stratifications around top dead center (TDC). Based on above, the pilot injections were specially designed to investigate ignition core formation and its effects on natural gas combustion process. The result shows that pilot ignition sites have great impacts on pilot fuel ignition process and natural gas combustion process. The pilot ignition site on the region with rich NG/Air mixture is disadvantageous to the pilot fuel ignition due to a lack of oxygen, which is not beneficial to ignition core formation.