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SOC (State of charge) plays an important role in vehicle energy management, utilization of battery pack capacity, battery protection. Model based SOC estimation algorithm is widely regarded as an efficient computing method, but battery model accuracy and measuring noise variance will greatly affect the estimation result. This paper proposed an adaptive mixed estimation algorithm. In the algorithm, the recursive least squares algorithm was used to identify the battery parameters online with a second-order equivalent circuit model, and an adaptive unscented Kalman method was applied to estimate battery SOC. In order to verify the effect of the proposed algorithm, the experimental data of a lithium battery pack was applied to build a simulation model. The results show that the proposed joint algorithm has higher estimation accuracy and minimum root mean square error than other three algorithms.