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The drive towards improved fuel economy and lower emissions for Diesel vehicles requires the development of catalysts capable of converting not only carbon monoxide (CO) and hydrocarbon (HC), but also particulate matter (PM) and nitrogen oxides (NOx) in a lean exhaust environment. This paper reviews the approaches that are being considered for this purpose, for light duty Diesels, together with factors that may influence catalyst performance such as components in the fuel and quality of the lubricant.

Future US emissions limits are likely to mean a sophisticated nitrogen oxide (NOx) reduction technique is required for all vehicles with a diesel engine, which is likely to be either NOx trap or selective catalytic reduction (SCR) technology. To investigate the potential of SCR for NOx reduction on a light duty vehicle, a current model vehicle (EUII M1 calibration), of inertia weight 1810 kg, was equipped with an urea-based SCR injection system and non-vanadium, non-zeolitic SCR catalysts. To deal with carbon monoxide (CO), hydrocarbon (HC) and volatile organic fraction (VOF), a diesel oxidation catalyst was also incorporated into the system for most tests. Investigations into the effect of placing the oxidation catalyst at different positions in the system, changing the volume of the SCR catalysts, increasing system temperature through road load changes, varying the SCR catalyst composition, and changing the urea injection calibration are discussed.

Reduction of nitrogen oxides in Diesel exhaust gas is a challenging task. This paper reports results from an extensive study using Pt-based catalysts involving synthetic gas activity testing (SCAT), engine bench testing and tests on passenger cars. Preliminary SCAT work highlighted the importance of Pt-dispersion, and both SCAT and bench engine testing yielded comparable NOx conversions under steady state conditions at high HC:NOx ratios. On passenger cars in the European cycle without secondary fuel injection NOx conversion was lower than obtained in the steady state tests. Better conversion was obtained in the FTP cycle, where secondary injection was employed. Higher HC:NOx, ratios and more favourable temperature conditions which were present in the exhaust contributed to this higher conversion.

The low exhaust gas temperatures experienced on light duty Diesel vehicles present a very challenging environment for the successful operation of catalytic aftertreatment. To meet the future more severe legislation, Diesel engines are being developed with greater combustion efficiencies and advanced fueling control. These engine developments may produce lower particulate matter (PM) and nitrogen oxides (NOx) emissions, but increased hydrocarbon (HC) and carbon monoxide (CO) emissions may occur. As a result of these engine changes exhaust gas temperatures may reduce still further. These factors demand catalysts with high oxidation activity at low temperatures. This paper reviews oxidation catalyst technology developed for light duty Diesel vehicles and the factors affecting their performance. Results obtained on synthetic gas rigs, bench engines and vehicles are presented. A discussion oh the effect of the level of sulfur (S) present in Diesel fuel on aftertreatment is given.