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The effects of the addition of small amounts of molecular and atomic hydrogen/oxygen on laminar burning velocity, pollutant concentrations, and adiabatic flame temperatures of premixed, laminar, freely propagating iso-octane flames are investigated using CHEMKIN kinetic simulation package and a chemical kinetic mechanism at different equivalence ratios. It is shown that hydrogen/oxygen additives increase the laminar burning velocities. Increased hydroxyl (OH) concentrations resulted in reduced carbon monoxide (CO) emissions in every stoichiometric ratios investigated. Additives also increased the adiabatic flame temperature of iso-octane/air combustion, thereby causing increased NOx concentrations for all additives at all stoichiometries.

This paper investigates the expansion of the HCCI operating range and combustion control by use of internal fuel reforming with subsequent reduction of NO emissions through Exhaust Gas Recirculation (EGR). The study is focused on multi-step simulation of the engine cycle, comprised of a fuel reformation cycle and a HCCI combustion cycle, with and without EGR. The study is carried out using a single-zone well-stirred reactor model and established reaction mechanisms. The HCCI engine cycle is fueled with a lean mixture of air and ethanol. This study demonstrates that supplementing EGR with internal reforming reduces the NO emissions level. Furthermore, the study shows that internal fuel reforming extends the operational range of HCCI engines into the partial load region and is effective in the combustion onset control. However, the model requires several enhancements in order to moderate the cycle pressure rise and pressure magnitude, and to lower the cycle temperatures and NO emissions.