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A failure mode in engine components that undermines engine reliability is scuffing; defined as sudden catastrophic failure of sliding surfaces. Usually accompanied by a rapid rise in friction and temperature, occurrence of scuffing marks the end of the component's useful life. At Argonne National Laboratory, we recently developed low-friction amorphous carbon coatings with exceptional tribological properties. The present study evaluates the scuffing performance of three variations of the carbon coating deposited on H-13 steel surfaces and lubricated with base-stock and fully formulated synthetic Poly-alfa-olefin (PAO) lubricants. Using a ball-on-flat contact configuration in reciprocating sliding, we found that although the coatings reduced friction slightly, they increased scuffing resistance significantly when one of the sliding surfaces was coated when compared to uncoated steel-on-steel contact.

Increased use of higher-efficiency compression ignition direct injection (CIDI) diesel fueled engines instead of today's gasoline engines will result in reduced fuel consumption and greenhouse gases emissions. However, nitrogen oxides (NOx) and particulate exhaust emissions from diesel engines must be significantly reduced due to their possible adverse health effects. Exhaust gas recirculation (EGR) is an effective way to reduce NOx emissions from diesel engines, but the particulates and acidic exhaust products in the recirculated gas will contaminate engine lubricant oil by increasing the soot content and total acid number (TAN). These factors will increase the wear rate in many critical engine components and seriously compromise engine durability. We have investigated the use of commercially available thin and hard coatings (TiN, TiCN, TiAlN, and CrN) to mitigate the negative effects of EGR on wear.