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The effect of crevice volumes on the emissions of unburned hydrocarbons from a Homogeneous Charge Compression Ignition (HCCI) engine has been experimentally investigated. By varying the size and the geometry of the largest crevice, the piston topland, it was possible to ascertain whether or not crevices are the largest source of HC. Additionally, information on quenching distances for ultra lean mixtures was obtained. The tests were performed on a single cylinder engine fuelled with iso-octane. The results showed that most of the unburned hydrocarbons descend from the crevices. Increasing the topland width to some degree lead to an increase in HC. A further increase in topland width (>1.3 mm) resulted in a reduction of HC when using mixtures richer than λ ≈ 2.8, indicating that some of the mixture trapped in the topland participates in the combustion. In conditions when combustion occurred in the topland, the HC was rather insensitive to the height of the topland.

An experimental and theoretical study of the effect of thermal barriers and catalytic coatings in a Homogeneous Charge Compression Ignition (HCCI) engine has been conducted. The main intent of the study was to investigate if a thermal barrier or catalytic coating of the wall would support the oxidation of the near-wall unburned hydrocarbons. In addition, the effect of these coatings on thermal efficiency due to changed heat transfer characteristics was investigated. The experimental setup was based on a partially coated combustion chamber. The upper part of the cylinder liner, the piston top including the top land, the valves and the cylinder head were all coated. As a thermal barrier, a coating based on plasma-sprayed Al2O3 was used. The catalytic coating was based on plasma-sprayed ZrO2 doped with Platinum. The two coatings tested were of varying thickness' of 0.15, 0.25 and 0.6 mm. The compression ratio was set to 16.75:1.