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A methodological analysis of combustion parameters and pollutant emissions measuring procedures during transient operation of a D.I. T.C. light duty diesel engine was performed. Combustion process was characterized by ignition delay time, combustion pressure peak value and heat release law measurements during the transient ECE 15 schedule on a dynamic test bed with electronic simulation of inertia. The particulate emission was measured every 0.05 s by an I.R. optical method. In addition some correlations, based on pressure cycle and injection law evolution, were implemented in order to calculate instantaneous fuel delivery and transient NOx emission. Some activities were carried out in order to asses the limits of engine configurations ranking performed with steady state measurements of performances and emissions. Strong differences were detected between carbon emission during transient operations and the value obtained by interpolation from a steady state map.

Three dimensional computations of Diesel combustion were performed using a modified version of Kiva II code. The autoignition and combustion model were tuned on a set of experimental conditions, changing the engine design, the operating conditions and the fuel characteristics. The sensitivity of the model to the different test cases is acceptable and the experimental trends are well reproduced. In addition the peak of pressure and temperature computed by the code are quite close to the experimental values, as well as the pressure derivatives. Once tuned the combustion model constants, different but simple formulations for the soot formation and oxidation processes were implemented in the code and compared with the experimental measurements obtained both with fast sampling technique and two colors method. These formulations were found unable to give good prediction in a large range of engine operating conditions, even if the model tuning may be very good for each test point.

Cetane number, sulphur content and aromatic structure of Automotive Diesel Oil (ADO) were changed to assess their influence on emissions of light duty direct injection Diesel engine. The detailed chemical analysis of particulate soluble fraction allows to quantify the P.A.Hs emission. In addition also the aldehydes and volatile organic compounds were measured in the gaseous phase. The sulphur content of the fuel and its aromatic structure strongly influence particulate emission. The insoluble fraction of the particulate rises with an increase of the high sulphur content ADOs with about the same back end volatility. Unburned P.A.Hs control P.A.Hs emission at the part loads typical of normalized schedules for emission testing of light duty vehicles in Europe. Finally the level of emissions of benzene and 1-3 butadiene is comparable to the total P.A.Hs emission.