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With the increasing level of electrification of on-road, off-road and stationary applications, use of larger lithium-ion battery packs has become essential. These packs require large capital investments on the order of millions of dollars and pose a significant risk of self-annihilation without rigorous safety evaluation and management. Testing these larger battery packs to validate design changes can be cost prohibitive. A reliable numerical simulation tool to predict battery thermal runaway under various abuse scenarios is essential to engineer safety into the battery pack design stage. A comprehensive testing & simulation workflow has been established to calibrate and validate the numerical modeling approach with the test data for each of the individual sub model - electrochemical, internal short circuit and thermal abuse model. A four-equation thermal abuse model was built and validated for lithium-ion 21700 form factor cylindrical cells using NCA cathodes.

As advances in electrification continue within the vehicle industry, improving the front-end design process and managing the safety aspects of lithium-ion batteries is increasingly important. Structural damage to lithium-ion batteries can cause internal short circuit, leading to a large energy release that can lead to fire and thermal runaway that propagates throughout the battery pack. Southwest Research Institute has developed a mechanical model that can accurately predict mechanically-induced damage to lithium-ion battery cells and battery packs. This model also predicts whether the external damage will cause an internal short-circuit. This modeling process was illustrated using 21700 cylindrical cells with NCA cathode chemistry. High-speed impact tests were used to calibrate a single cell model, which was then scaled to a 12-cell battery module. This model was then used to accurately predict the outcome of an impact test on a 72-cell battery module.