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Technical Paper

Plasma-Assisted Catalytic Reduction of NOx

1998-10-19
982508
Many studies suggest that lean-NOx SCR proceeds via oxidation of NO to NO2 by oxygen, followed by the reaction of the NO2 with hydrocarbons. On catalysts that are not very effective in catalyzing the equilibration of NO+O2 and NO2, the rate of N2 formation is substantially higher when the input NOx is NO2 instead of NO. The apparent bifunctional mechanism in the SCR of NOx has prompted the use of mechanically mixed catalyst components, in which one component is used to accelerate the oxidation of NO to NO2, and another component catalyzes the reaction between NO2 and the hydrocarbon. Catalysts that previously were regarded as inactive for NOx reduction could therefore become efficient when mixed with an oxidation catalyst. Preconverting NO to NO2 opens the opportunity for a wider range of SCR catalysts and perhaps improves the durability of these catalysts. This paper describes the use of a non-thermal plasma as an efficient means for selective partial oxidation of NO to NO2.
Technical Paper

Effective Rhodium Utilization in Automotive Exhaust Catalysts

1986-03-01
860566
On vehicles equipped with fuel shut-off, the rhodium in conventional TWC catalyst tends to strongly interact with the washcoat components during the high temperature lean excursions seen during deceleration. Studies were conducted to elucidate the conditions under which rhodium interacts with the alumina washcoat support and the rare earth components used in some of the new “High Tech” catalyst compositions. Technology was developed which decreased the rhodium interaction with these washcoat components which permits the catalyst to operate under a much broader set of engine control conditions. Laboratory hydrothermal and engine dynamometer aging studies were used to demonstrate the feasibility of lowering precious metal usage and especially rhodium content of TWC catalysts without sacrificing “High Tech” performance.
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