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Recent years have seen dramatic reductions in gasoline and diesel sulfur concentrations in the United States, Europe, Japan and other countries. Many developing countries are evaluating the appropriate sulfur levels to choose for the future. This paper examines the current state of knowledge concerning the impact of fuel sulfur on exhaust emissions, and the sensitivity of exhaust aftertreatment technology to fuel sulfur. Gasoline vehicles achieve very low emissions through use of three-way catalysts. These systems are relatively insensitive to sulfur, being able to operate on levels of up to 500 ppm. Further reduction in sulfur will produce additional, small emission reductions. Diesel emissions may be reduced significantly using engine modifications, oxidation catalysts or exhaust gas recirculation, which may require sulfur levels of 500 ppm.

Particle emissions from vehicles are currently under close scrutiny with respect to their contribution to ambient air quality relative to other sources. Small particles, less than 10 μm, referred to as PM10, have been linked to various health issues. In this study, tests have been performed on European diesel light duty vehicles using a range of production diesel fuels. Tests were also performed on two gasoline passenger cars for comparison. Measurements were made of exhaust particle size distribution and number, as well as mass emissions using the legislated filter paper method. The results showed that most of the particles emitted were very small, with median size of the order 100 nanometres (nm). The median particle size was insensitive to changes in fuel, vehicle or operating condition. Measurements of particle number broadly correlated with particle mass emissions, and ranked fuels and vehicle types in the same order.