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Exhaust emission and performance characteristics of a single-cylinder engine fueled with methanol are compared to those obtained either with gasoline or a methanol-water blend. Our measurements of engine efficiency and power, and CO and NOx emissions agree with trends established in the literature. Consequently, the emphasis is placed on organic emissions (unburned fuel including hydrocarbons, and aldehydes), an area in which there is no consensus in the literature. In all cases with methanol fueling, the unburned fuel (UBF) emissions were virtually all methanol as opposed to hydrocarbon compounds. Without special measures to overcome methanol's large heat of vaporization, UBF emissions were four times greater with methanol than those with gasoline. Similarly, aldehyde emissions were an order of magnitude greater with methanol.