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Close coupled catalysts and new ceramic catalyst substrates have significantly improved the light-off performance of automotive converters required to meet stringent emission requirements. The hotter environment of these catalytic converters and the lower structural strength of the ceramic substrates require the rethinking of converter designs. The development of new package requirements to accommodate the change in environment and new substrates are discussed. A historical perspective on converter durability is presented as reference. Development of durability test protocols is essential to verifying product durability performance to these new environments. Data collection and documentation of testing templates are shown to demonstrate the effectiveness of tests that represent real world environments. Design improvements to address failure modes are discussed along with durability improvement results.

The emission and flow restriction characteristics of three different ceramic substrates with varying wall thickness and cell density (400 cpsi/6.5 mil, 600/4.3, and 600/3.5) are compared. These 106mm diameter substrates were catalyzed with similar amounts of washcoat and fabricated into catalytic converters having a total volume of 2.0 liters. A Pd/Rh catalyst technology was applied at a concentration of 6.65 g/l and a ratio of 20/1. Three sets of converters (two of each type) were aged for 100 hours on an engine dynamometer stand. After aging, the FTP performance of these converters were evaluated on an auto-driver FTP stand using a 2.4L, four-cylinder prototype engine and on a 2.4L, four-cylinder prototype vehicle. A third set of unaged converters was used for cold flow restriction measurements and vehicle acceleration tests.

FTP and ECE + EUDC emissions are measured from six converters having similar restriction and platinum group metals on two 1999 prototype engines/calibrations. A 2.2L four cylinder prototype vehicle is used to measure FTP emissions and an auto-driver dynamometer with a prototype 2.4L four cylinder engine is used to determine the ECE + EUDC emissions. The catalytic converters use various combinations of 400/3.5 (400cpsi/3.5mil wall), 400/4.5, 400/6.5, 600/3.5, 600/4.5, and 900/2.5 ceramic substrates in order to meet a restriction target and to maximize converter geometric surface area. Total catalyst volume of the converters varies from 1.9 to 0.82 liters. Catalyst frontal area varies from 68 cm2 to 88 cm2. Five of the six converters use two catalyst bricks. The front catalyst brick uses either a three-way Pd washcoat technology containing ceria or a non-ceria Pd washcoat technology. Pd loadings are 0.1 troy oz. of Pd.